Adhesion Of Teeth
Write a short note on BisGMA and TEGDMA.
Answer:
BisGMA is one of the first multifunctional methacrylates used in dentistry.
- BisGMA was developed by RL Bowen (Bowen resin) in the early 1960s.
- The BisGMA resin is an aromatic ester of a methacrylate, synthesized from an epoxy resin (ethylene glycol of phenol A) and methyl methacrylate.
- Because BisGMA has two-OH groups that form hydrogen bonds between the monomers, it is extremely viscous.
- The high viscosity of BisGMA makes it very difficult to blend and manipulate, thus it is necessary to use lower molecular weight, highly fluid monomers to dilute BisGMA.
- A low-viscosity methacrylate such as trimethylene glycol dimethacrylate (TEGDMA) is blended with it to reduce viscocity.
- TEGDMA also has the advantage of producing extensive cross-linking among polymer chains. This results in a rigid resin matrix that is highly resistant to softening and/or degradation by heat and solvents such as water and alcohol.
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